Journal
ORGANIC LETTERS
Volume 9, Issue 18, Pages 3675-3678Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol701685y
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Chiral amine and polyoxometalate (POM) acids were combined to give highly efficient, stereoselective, and recoverable enamine-based catalysts. Less than 1 mol % of chiral amine loading was sufficient for good catalytic activity, and the catalyst could be recovered and reused 6 times with unchanged enantioselectivity and slightly decreased activity.
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