Journal
ORGANIC LETTERS
Volume 9, Issue 18, Pages 3539-3542Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol071402f
Keywords
-
Categories
Ask authors/readers for more resources
We have reported an efficient gold(I)-catalyzed tandem cyclization of tert-butyl carbonate derivatives of hex-1-en-5-yn-3-ol where nucleophilic participation of the O-Boc group appears to intercept a carbocationic (or cyclopropyl carbene) Au intermediate. This novel protocol leads to densely functionalized cyclohexene-3,4-diol derivatives where 1,2- or 1,2,3-stereocenters are controlled in a highly diastereoselective fashion.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available