4.8 Article

Platinum(II) - Coordinated phosphinous acid-catalyzed alkylidenecyclopropanation of bicyclic alkenes with terminal alkynes

Journal

ORGANIC LETTERS
Volume 9, Issue 18, Pages 3567-3570

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol071386m

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New Pt(eta(2)-acetato){[(R)(Ph)PO](2)H} complexes 3 prepared from PtCl2(CH3CN)(2) and secondary phosphine oxides (SPOs) catalyzed the [2 + 1] cycloaddition of phenylethyne (5a) with norbornene derivatives 4 to afford benzylidenecyclopropanes.

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