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The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-donor ligands

Journal

POLYHEDRON
Volume 26, Issue 14, Pages 3523-3576

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2007.03.033

Keywords

n-donor ligands; iron complexes; spin-crossover; magnetic measurements; crystallography

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A survey of mononuclear iron(II) complexes with heterocyclic N-donor ligation is presented. A brief introduction to spin-crossover chemistry and low-temperature spin-trapping is provided, since many of these compounds undergo thermal spin-transitions upon cooling or heating. These are highlighted, and the structural changes underlying spin-crossover are discussed where this is known. Materials showing spin-trapping behaviour following thermal quenching or irradiation at very low temperatures are also described. (c) 2007 Elsevier Ltd. All rights reserved.

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