Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 349, Issue 13, Pages 2129-2135Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200700155
Keywords
asymmetric catalysis; Morita-Baylis-Hillman reaction; NMR spectroscopy; organic catalysis; thiourea-phosphine organocatalysts
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A new kind of bifunctional (thio)ureapbosphine catalyst was synthesized and applied to the aza-Morita-Baylis-Hillman reaction of N-sulfonated imines with methyl vinyl ketone, phenyl vinyl ketone, ethyl vinyl ketone or acrolein. Moderate to excellent ee and yields of the products were obtained under mild reaction conditions.
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