Journal
ANALYTICA CHIMICA ACTA
Volume 653, Issue 1, Pages 103-108Publisher
ELSEVIER
DOI: 10.1016/j.aca.2009.08.043
Keywords
Optical sensor; Molecularly imprinted polymer film; Formaldehyde; Optical intensity
Categories
Funding
- National Science Foundation of china [20375029]
- National Key Laboratory of Chemo/Biosensing and Chemometrics of Hunan University.
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A novel and highly selective optical sensor with molecularly imprinted polymer (MIP) film was fabricated icated and investigated The optical sensor head employing a medium finesse molecularly imprinted polymer film has been fabricated and characterised A blank polymer and formaldehyde imprinted polymer were using methacrylic acid as the functional monomer and the ethylene glycol dimethacrylate as a crosslinker The transduction mechanism is discussed based on the changes of optical intensity of molecularly imprinted polymer film acting as an optical reflected sensor. Template molecules, which diffused into MIP. could cause film density, and refractive index change, and then induce measurable optical reflective intensity shifts Based on the reflective intensity shifts, an optical reflection detection of formaldehyde was achieved by illuminating MIP with a laser beam For the same MIP. the reflective intensity shift was proportional to the amount of template molecule. This optical sensor, based on an artificial recognition system. demonstrates long-time stability and resistance to harsh chemical environments As the research moves forward gradually. we establish the possibilities Of quantitative analysis primly. setting the groundwork to the synthesis of the molecular imprinted optical fiber sensor. The techniques show good reproducibility and sensitivity and will be of significant interest to the MIP community (C) 2009 Elsevier B.V. All rights reserved
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