4.3 Article

Oxidation of unsaturated compounds in ionic liquids with the use of cyclodextrin-containing catalytic systems

Journal

PETROLEUM CHEMISTRY
Volume 47, Issue 5, Pages 331-336

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0965544107050039

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The Wacker oxidation of alkenes-1 in ionic liquids catalyzed by a system containing palladium, and copper complexes and beta-cyclodextrins was studied. It was shown that the use of beta-cyclodextrins substantially increases the oxidation rate in biphasic systems olefin/ionic liquid. It was found that the proposed catalytic systems possess substrate selectivity, which is determined by the structure of a receptor molecule.

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