4.6 Article

Selective hydrogenation of m-dinitrobenzene to m-nitroaniline. catalyzed by PVP-Ru/Al2O3

Journal

CATALYSIS COMMUNICATIONS
Volume 8, Issue 9, Pages 1305-1309

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2006.11.033

Keywords

selective hydrogenation; m-dinitrobenzene; m-nitroaniline; ruthenium; metal cations

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Selective hydrogenation of m-dinitrobenzene to m-nitroaniline (m-NA) catalyzed by polylvinylpyrrolidone stabilized Ru/Al2O3 (PVPRu/Al2O3) was studied experimentally. The effects of solvents, metal cation additives and reaction conditions were examined. The highest total yield of m-NA was obtained with 97.9% selectivity at 100% conversion when Sn4+ used as modifier (the molar ratio of m-DNB to catalyst was 477:1, the molar ratio of Sn4+ to ruthenium was 1:4) under suitable conditions. (c) 2006 Elsevier B.V. All rights reserved.

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