4.0 Article

An NMR study of the equilibration of D-glucaric acid with lactone forms in aqueous acid solutions

Journal

JOURNAL OF CARBOHYDRATE CHEMISTRY
Volume 26, Issue 7-9, Pages 455-467

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/07328300701787172

Keywords

D-glucaric acid; lactones; equilibration; NMR; kinetic modeling

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The aqueous solution equilibration of D-glucaric acid with its lactone forms was studied by NMR with and without acid catalysis. The kinetics of the approach to equilibrium were simulated, and approximate equilibrium and rate constants were obtained.

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