Journal
PHYSICAL REVIEW A
Volume 76, Issue 3, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.76.032706
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The dispersion coefficients for the van der Waals interactions between the rare gases Ne, Ar, Kr, and Xe and the low-lying states of Li, Na, K, and Rb are estimated using a combination of ab initio and semiempirical methods. The rare-gas oscillator strength distributions for the quadrupole and octupole transitions were derived by using high-quality calculations of rare-gas polarizabilities and dispersion coefficients to tune Hartree-Fock single-particle energies and expectation values.
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