4.6 Article

A near-infrared and ratiometric fluorescent chemosensor for palladium

Journal

ANALYST
Volume 138, Issue 13, Pages 3667-3672

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3an00616f

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Funding

  1. NSF of China [21222605, 21006009, 21136002, 21076032, 20923006]
  2. Fundamental Research Funds for the Central Universities of China, 973 program of China [2009CB724700, 2012CB733702]
  3. 863 program of China [2011AA02A105]

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A near-infrared chemosensor for palladium based on the Tsuji-Trost reaction was developed. It displayed specific and ratiometric fluorescent responses toward palladium with a distinct color change from green to blue in aqueous media. PEG400 was employed as the reducing agent and palladium ligand instead of water-insoluble triphenylphosphine. The chemosensor's bioimaging potential was demonstrated by in vitro and in vivo experiments.

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