4.2 Article

Reactions of boron trifluoride with allylic boranes and 1-boraadamantane

Journal

MENDELEEV COMMUNICATIONS
Volume 17, Issue 5, Pages 271-273

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ELSEVIER
DOI: 10.1016/j.mencom.2007.09.007

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The reactions of boron trifluoride with triallyl- and allyldialkylboranes represent a convenient non-catalytic approach to allyl(difluoro)boranes. The rupture of 1-boraadamantane core with BF3 leads to 3-fluoro-7-difluoroborylmethyl-3-borabicyclo-[3.3.1]nonane derivatives.

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