Journal
ANALYST
Volume 135, Issue 10, Pages 2682-2687Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0an00201a
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Funding
- Natural Science Foundation of China [20975116]
- SRF for ROCS, SEM
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A novel localized surface plasmon resonance (LSPR) light-scattering sensor for Ag+ was developed with unmodified gold nanoparticles (AuNPs), based upon the specific recognition property of Ag+ with a cytosine-cytosine mismatched base pair. The addition of Ag+ induced the oligonucleotide 5'-TAC ATA CAT ACT ATC TAT CTA-3' to be desorbed from the surface of the AuNPs, resulting in the aggregation of AuNPs, accompanied by a dramatic enhancement of the LSPR light-scattering intensity. The enhancement of LSPR light-scattering intensity was proportional to the concentration of Ag+ in the range of 0.13-1.12 mu M, with a limit of detection of 62.0 nM. The results were also proved by a colorimetric method. Furthermore, this method can provide satisfactory results for the determination of Ag+ in water samples and industrial products.
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