Journal
CARBOHYDRATE RESEARCH
Volume 342, Issue 12-13, Pages 1689-1703Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2007.05.021
Keywords
carbasugars; fluorine; mimics; inositol
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5a-Difluoro-5a-carbamannopyranose (gem-difluoro-carbamannopyranose) and 5a-difluoro-5a-carbagalactopyranose (gem-di-difluoro-carbagalactopyranose), close congeners of their respective natural sugars, in which the endocyclic oxygen atom has been replaced by a gem-difluoromethylene group, were synthesized from D-mannose and D-galactose, using a rearrangement strategy. (c) 2007 Elsevier Ltd. All rights reserved.
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