Journal
SYNLETT
Volume -, Issue 14, Pages 2193-2196Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-984911
Keywords
zincate. BINOL; alpha-keto ester; asymmetric organometallic addition; trifluoropyruvate
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A chromatography-free synthesis of enantiomerically enriched chiral a-trifluoromethyl alpha-hydroxy acids prepared via an asymmetric (R)-BINOL-mediated organozincate addition to ethyl,2,2-trifluoropyruvate (1) is reported.
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