Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 36, Pages 10992-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja0732936
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Robust syndiotactic polystyrene films, presenting a suitable nanoporous host crystalline phase, are able to transfer, amplify, and memorize the chirality of nonracemic low-molecular-mass molecules. In fact, after temporary exposure to volatile nonracemic guests, the polymer films present intense induced circular dichroism (ICD) phenomena. These ICD phenomena are associated with the temporary formation of polymer/guest cocrystalline phases.
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