Journal
ORGANIC LETTERS
Volume 9, Issue 19, Pages 3725-3728Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol7014253
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Intramolecular ring closing alkyne metathesis afforded the graphyne biscyclyne (3) in high macrocyclization yield and good overall yield. This methodology also furnished the tris[12]cyclyne 4, which contains the longest linear diphenylacetylene conjugation pathway for any graphyne substructure based on the tribenzo[12]cyclyne core.
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