4.8 Article

An original redox-responsive ligand based on a π-extended TTF framework

Journal

ORGANIC LETTERS
Volume 9, Issue 19, Pages 3753-3756

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol7015127

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The synthesis of the first :pi-extended tetrathiafulvalene (TTF) ligand featuring a furanoquinonoid spacer and pyridyl functional groups is described. This compound shows an unprecedented electrochemical sensing behavior and excellent coordinating properties toward selected divalent metal ions. Solid-state structures of the free ligand and its Ni(II)Cl-2 complex are described.

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