4.8 Article

Ruthenium-catalyzed cross-metathesis between diallylsilanes and electron-deficient Olefins

Journal

ORGANIC LETTERS
Volume 9, Issue 19, Pages 3765-3768

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol0712632

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Diallysilanes can be selectively coupled with electron-deficient olefins under cross-metathesis (CM) conditions using the Hoveyda-Grubbs catalyst to produce mono- and/or bis-CM compounds in good yield. The formation of the mono- and the bis-CM compounds depends on the nature of the electron-deficient olefin.

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