Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 19, Pages 7435-7438Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo070962p
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[GRAPHICS] A new chiral benzimidazolide is developed as a nonenzymatic acylating agent for enantioselective benzoylation of racemic cc-amino esters. The process is highly efficient, which exhibits uniformly high enantioselectivity for alpha-amino esters with or without aryl substituents under mild reaction conditions. The chiral benzimidazolide is inexpensive and is easily accessible.
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