Journal
SYNLETT
Volume -, Issue 15, Pages 2436-2438Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-986638
Keywords
triazole; copper(II) triflate; click reaction
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Copper(II) triflate doubly catalyzed the substitution of benzylic acetates by TMSN3 and the subsequent 1,3-dipolar addition with an alkyne in one pot. This procedure afforded the preparation of 1,4-disubstituted 1,2,3-triazoles in good yields starting from the easily accessible acetates without isolating an organic azide using a single catalyst.
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