Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 37, Pages 11340-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja075245r
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Funding
- NIGMS NIH HHS [R01-GM62871] Funding Source: Medline
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A method has been developed for achieving palladium-catalyzed intramolecular Heck reactions of unactivated, beta-hydrogen-containing alkyl bromides and chlorides. The data from a stereochemical investigation are consistent with carbon-carbon bond formation via an alkylpalladium, rather than a radical, intermediate.
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