Journal
POLYMER
Volume 48, Issue 20, Pages 5813-5833Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2007.07.031
Keywords
alkoxyamine; nitroxide-mediated controlled/living free-radical polymerization; emulsion polymerization
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This feature article describes the application of nitroxide-mediated controlled/living free-radical polymerization in aqueous dispersed systems such as miniemulsion and emulsion polymerizations. It mainly focuses on the acyclic nitroxide SG1 with derived alkoxyamines and aims to show how the recent development of new water-soluble species has allowed a true emulsion polymerization process to be successfully implemented and block copolymers to be created directly in latex particles. (c) 2007 Elsevier Ltd. All rights reserved.
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