Journal
TETRAHEDRON LETTERS
Volume 48, Issue 39, Pages 6860-6862Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.07.181
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Oxidation of cyclohexanones into conjugated enones with molecular oxygen as oxidant was achieved by palladium catalysts. A catalyst system consists of I mol % Pd(OCOCF3)(2) and 5,5'-dimethyl-2,2'-bipyridine accomplished maximum 84% yield for the oxidation of cyclohexanone and 51-78% yields for 4-SLibstituted-cyclohexanones. (C) 2007 Elsevier Ltd. All rights reserved.
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