Journal
TETRAHEDRON LETTERS
Volume 48, Issue 39, Pages 6845-6848Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.07.182
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An enantioselective approach to the spiroimine fragment of pinnatoxins is described. The strategy is based on a recently developed diastereoselective Ireland-Claisen rearrangement to establish the challenging congested quaternary and tertiary stereocenters within the cyclohexene ring. (C) 2007 Elsevier Ltd. All rights reserved.
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