Journal
CHEMICAL PHYSICS LETTERS
Volume 446, Issue 1-3, Pages 31-35Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2007.08.044
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Funding
- Ministry of Education, Science & Technology (MoST), Republic of Korea [kaist36, 07-2404-022] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [과06A1506] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Photodissociation dynamics of CF3Br has been investigated at 225 nm, where the (3)Q(0) state is accessed exclusively. It has been revealed that the ground state Br(P-2(3/2)) is hardly formed with a relative quantum yield less than 5%. The recoil anisotropy of Br *((2)p(1/2)) has been found to have a limiting value, beta(Br*) = 1.90 +/- 0.05. The total translational energy distribution for the Br* channel was well fitted by a Gaussian function with an average of 155 kJ/mol and a width of 30 KJ/mol. It has been proposed that the (3)Q(0) state is not bent and the dissociation on this surface proceeds in a collinear geometry. (C) 2007 Elsevier B.V. All rights reserved.
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