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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 38, Pages 11850-11853Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja073900p
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The interconversion between helical diastereomers of nickel-salen-based foldamers can be observed on a NMR time scale. Such complexes provide quantitative information about the propensity of different elements of central chirality to control the absolute sense of folding. trans-Cyclohexane-1,2-diamine-a common component of chiral salen catalysts-is a surprisingly weak director of absolute helicity in nickel-salen foldamers. Implications for asymmetric catalysis are discussed.
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