Journal
ORGANIC LETTERS
Volume 9, Issue 20, Pages 3969-3972Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol701692m
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- NIGMS NIH HHS [GM066055] Funding Source: Medline
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A Rh(l)-catalyzed asymmetric [2 + 2 + 2] cycloaddition of achiral ynamides is described here. This work demonstrates a unique concept of stereochemical control of both the C-C and C-N axial chirality and provides an approach to the synthesis of chiral N,O-biaryls as well as chiral anilides.
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