Journal
ORGANIC LETTERS
Volume 9, Issue 20, Pages 3865-3868Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol701618n
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A photoresponsive molecularly imprinted polymer was prepared from a di(ureidoethylenemethacrylate)azobenzene monomer, using a methotrexate analogue as template. Photoisomerization of the 3D crosslinked polymer matrix allowed switching the substrate affinity by altering the geometry and spatial arrangement of the receptor binding sites. As a result, controlled release and uptake of the template (or analogous ligands) were obtained.
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