Journal
ORGANIC LETTERS
Volume 9, Issue 20, Pages 3957-3959Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol701544z
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Benzylic hydrocarbons are selectively converted to the corresponding sulfonamides by the [Cu(CH3CN)(4)]PF6-catalyzed reaction with anhydrous TolSO(2)NNaCl (chloramine-T). Under the same conditions, representative ethers are also alpha-amidated; olefins produce allyl sulfonamides, aziridines, and/or,beta-chloro sulfonamides.
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