Journal
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS
Volume 46, Issue 36-40, Pages L945-L947Publisher
INST PURE APPLIED PHYSICS
DOI: 10.1143/JJAP.46.L945
Keywords
Prussian blue; nanoparticle; thin film; electrochromic; wet process
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Electrochromic thin films of Prussian blue nanoparticles were developed using wet processing. The resultant alkyl-ligand covered nanoparticles disperse well in organic solvents. Consequently, various conventional coating and printing methods can be used in high-quality micro-fabrication to prepare electronic devices. We examined electrochromic properties of the thin film fabricated using spin-coating method. Electrochromism of the thin film on an indium tin oxide (ITO) electrode was observed. The color changes from blue to colorlessness reversibly at potentials between +0.6 to -0.4 V. Furthermore, various patterns were printed on ITO substrates using photolithography, indicating potential application of this approach to information displays and smart windows.
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