Journal
JOURNAL OF LUMINESCENCE
Volume 126, Issue 2, Pages 371-377Publisher
ELSEVIER
DOI: 10.1016/j.jlumin.2006.08.093
Keywords
photoluminescence; YAG:Ce; phosphor; white LEDs; color rendering
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We have enhanced color-rendering property of a blue light emitting diode (LED) pumped white LED with yellow emitting Y3Al5O12:Ce3+ (YAG:Ce) phosphor using addition of Pr and Tb as a co-activator and host lattice element, respectively. Pr3+ addition to YAG:Ce phosphor resulted in sharp emission peak at about 610nm through D-1(2) -> H-3(4) transition. And when Tb3+ substituted Y3+ sites, Ce3+ emission band shifted to a longer wavelength due to larger crystal field splitting. Y3Al5O12:Ce3+, Pr3+ and (Y1-xTbx)(3)Al5O12:Ce3+ phosphors were coated on blue LEDs to fabricate white LEDs, respectively, and their color-rendering indices (CRIs, R-a) were measured. As a consequence of the addition of Pr3+ or Tb3+, CRI of the white LEDs improved to be R-a = 83 and 80, respectively. Especially, blue LED pumped (Y0.2Tb0.8)(3)Al5O12:Ce3+ white LED showed both strong luminescence and high color-rendering property. (c) 2006 Elsevier B.V. All rights reserved.
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