Journal
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Volume 59, Issue 1-2, Pages 11-15Publisher
SPRINGER
DOI: 10.1007/s10847-006-9151-9
Keywords
clathrate hydrate; ionic clathrate; phase diagram; structure; tetraalkylammonium salts
Categories
Ask authors/readers for more resources
The crystal structure of (C4H9)(4)NF center dot 29.7H(2)O clathrate hydrate (ionic clathrate) determined by X-Ray analysis is reported. The structure is cubic, I(4)over bar 3>d, a = 24.375(3) angstrom (150 K). Its idealized water framework is analogous to that of cubic structure-I of gas hydrates but with eight-fold unit cell, that is a superstructure of cubic structure-I. This is the last structure found in the binary system (C4H9)(4)NF-H2O which was not characterized by X-ray analysis earlier. The structure features of the compound under investigation and others existing in H2O-(C4H9)(4)NF binary system are discussed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available