4.3 Article

A novel N-linked peptidocalix[4]arene receptor for anions

Journal

SUPRAMOLECULAR CHEMISTRY
Volume 19, Issue 7, Pages 531-535

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/10610270601182850

Keywords

calixarene; fluorescent chemosensor; anion recognition; hydrogen bonding

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A novel N-linked fluorescent peptidocalix[4]arene functionalized with two L-phenylalanine and dansyl ethylenediamine units at the upper rim has been prepared. The fluorescence and H-1 NMR spectra were used to investigate its properties of molecular recognition for some important anions. This compound shows selective fluorescent response towards F- different from AcO-, H2PO4-, Cl-, Br-, NO3-, I- and HSO4-.

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