Journal
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 43, Issue 10, Pages 1421-1426Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1070428007100016
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Grignard reagents are able to add twice to nitriles in the presence of titanium(IV) isopropoxide providing primary tert-alkylamines in a fair yield. The conditions and structural features of reagents required for successful reaction were established. A possibility to apply two different organometallic reagents was demonstarated, in particular, the use of organolithium compounds in the second stage.
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