Journal
ORGANIC LETTERS
Volume 9, Issue 21, Pages 4207-4210Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol701770h
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A triptycene-based cylindrical macrotricyclic host can include diquat and electron-rich aromatics simultaneously to form stable ternary complexes, which is stabilized not only by a charge-transfer (CT) interaction between electron-rich and electron-deficient guests but also by the face to face pi-stacking interactions between the host and the guests. Moreover, a selective complexation process between a ternary complex containing benzidine and a binary complex can be effectively controlled by the use of acid and base.
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