Journal
ORGANIC LETTERS
Volume 9, Issue 21, Pages 4115-4118Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol701466u
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- NIGMS NIH HHS [R01 GM062160, GM62160, R01 GM062160-07] Funding Source: Medline
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The unexpectedly high reactivity of a (2-benzoxazolyl) per-O-benzoyl-beta-D-thioglucoside and related donors in reactions promoted by copper(II) trifluoromethanesulfonate is revealed, by comparison with the unreactive alpha-anomer, to be the result of neighboring group participation. Revision of the armed-disarmed concept for glycosyl donors is not required.
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