Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 21, Pages 8076-8086Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo701487j
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[GRAPHICS] The syntheses of (+/-)-dibromophakellstatin and, from this species, (+/-)-dibromophakellin are described. Oxidative cyclization of a phenylthiolated dihydrooroidin derivative triggered by a Pummerer reaction constitutes the key step in this biomimetic approach to this family of marine alkaloids.
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