Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 21, Pages 8127-8130Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo701354c
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[GRAPHICS] Sodium tetramethoxyborate, easily prepared by reaction of inexpensive sodium borohydride with methanol, possesses a suitable combination of a Lewis base and a Lewis acid to catalyze Michael reactions at room temperature under practically neutral conditions. This reaction provides good to excellent yields of Michael addition products from a broad scope of Michael donor and Michael acceptor reagents.
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