Journal
INORGANIC CHEMISTRY
Volume 46, Issue 21, Pages 8490-8492Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic7014034
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Funding
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0910761] Funding Source: National Science Foundation
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A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5)center dot xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 angstrom, the activated 1a exhibits highly selective sorption behavior toward H-2/N-2, H-2/CO, and CO2/CH4.
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