4.4 Article

A carbohydrate based approach towards the synthesis of aspercyclide C

Journal

TETRAHEDRON LETTERS
Volume 48, Issue 42, Pages 7524-7527

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.08.050

Keywords

chiron approach; ring closing metathesis (RCM); D-ribose; Ullmann coupling; Mukaiyama reagent

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A formal total synthesis of aspercyclide C (3) is described in which D-ribose is employed as a chiral pool material. The key step is a ring closing metathesis. (C) 2007 Elsevier Ltd. All rights reserved.

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