Journal
ADVANCED MATERIALS
Volume 19, Issue 20, Pages 3312-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200700188
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Funding
- EPSRC [EP/C545273/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/C545273/1] Funding Source: researchfish
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Nitrogen K-shell near-edge X-ray absorption fine structure (NEXAFS) measurements have been used for the first time to demonstrate 1D alignment of cobalt phthalocyanine (CoPc) molecules inside carbon nanotubes (see figure), revealing a stacking order consistent with the metastable alpha-CoPc phase. In addition, transmission electron microscopy images show pristine nanotubes surfaces and near-optimal filling. The smallest internal diameter to host CoPc molecules is found to be 15 angstrom.
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