Journal
JOURNAL OF CHROMATOGRAPHY A
Volume 1168, Issue 1-2, Pages 212-224Publisher
ELSEVIER
DOI: 10.1016/j.chroma.2007.07.018
Keywords
capillary electrophoresis; electrokinetic chromatography; polymer nanoparticles; silica nanoparticles; gold nanoparticles; carbon nanotubes; fullerenes
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Applications of nanoparticles are of rising interest in separation science, due to their favorable surface-to-volume ratio as well as their applicability in miniaturization. A stationary phase with large surface area in combination with an electroosmotic flow-driven system has great potential in a highly efficient separation system. This review covers the use of various nanoparticles as stationary or pseudostationary phase in capillary and microchip electrochromatography. The use of nanoparticles in pseudostationary phase capillary electrochromatography and open-tubular capillary electrochromatography are thoroughly discussed. The stationary and pseudostationary phases that are described include polymer nanoparticles, gold nanoparticles, silica nanoparticles, fullerenes and carbon nanotubes. (c) 2007 Elsevier B.V. All rights reserved.
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