Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 3, Issue -, Pages -Publisher
BEILSTEIN-INSTITUT
DOI: 10.1186/1860-5397-3-34
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Acyclic allylic monofluorides were prepared by electrophilic fluorination of branched (E)-allylsilanes with Selectfluor. These reactions proceeded with efficient transfer of chirality from the silylated to the fluorinated stereocentre. Upon double fluorination, an unsymmetrical ethyl syn-2,5-difluoroalk-3-enoic ester was prepared, the silyl group acting as an anti stereodirecting group for the two C-F bond forming events.
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