Journal
MACROMOLECULES
Volume 40, Issue 22, Pages 7928-7933Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma071357r
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The radical addition of mercaptans (RSH) onto poly [2-(3-butenyl)-2-oxazoline], which is available through a living/controlled cationic isomerization polymerization, can proceed smoothly in the absence of side reactions, exhibiting the characteristics of a click reaction. The thio-click reaction can be performed under feasible ([RSH]/[C=C] similar to 1.2-1.5, no transition metal additives) and mild conditions (generation of radical's with UV light at room temperature) and goes to completion within a day. Hydrophobic fluoropolymers can be prepared in the same way as water-soluble (co-)polymers or glycopolymers, starting from readily available materials.
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