Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 111, Issue 43, Pages 15700-15705Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp0737395
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In this paper, we discuss an extension of a field theoretical approach for the description of the double layer containing ions of finite size. In particular, the density profile and the differential capacitance are presented in the low-temperature regime, and excluded volume effects are discussed. Simple approximations are presented which allow for analytic expressions. Our results are compared to Monte Carlo simulation data.
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