Journal
ENVIRONMENTAL SCIENCE & TECHNOLOGY
Volume 41, Issue 21, Pages 7497-7502Publisher
AMER CHEMICAL SOC
DOI: 10.1021/es0708058
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While the reactivity of C-60 has been described in a variety of organic solvents, little information is available regarding aqueous-based reactions due to solubility limitations. In this study, a reaction between C-60, as a nanoscale suspension, and dissolved ozone in the aqueous phase was investigated. Findings indicate a facile reaction occurs, resulting in aggregate dissolution concurrent with formation of watersoluble fullerene oxide species. Product analyses, including C-13 NMR, MS (LDI), FTIR, UV-Vis, and XPS, indicate highly oxidized fullerene with an average of similar to 29 oxygen additions per molecule, arranged in repeating hydroxyl and hemiketal functionalities. These findings are significant in that they (1) demonstrate the feasibility of other aqueous-based fullerene chemistries, including those for alternative synthesis routes, which might otherwise be considered prohibitive on the basis,of solubility limitations, and (2) imply that the aqueous reactivity of fullerene-based materials must be considered appropriately for accurate assessment of their transport, fate, and potential risk(s) in environmental systems.
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