Journal
ACCOUNTS OF CHEMICAL RESEARCH
Volume 40, Issue 11, Pages 1208-1216Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ar7001649
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The solubilities of gases in ionic liquids are important in evaluating ionic liquids as solvents for reactions involving permanent gases, as gas storage media, and as solvents for gas separations. Gas solubilities are also important in developing methods to separate solutes from ionic liquid solutions. Here we describe our measurements of the solubilities of CO2, CH4, C2H6, C2H4, O-2, and N-2 in 1-hexyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide and compare these results to our previous investigations. In addition, focus is placed on efforts to tailor ionic liquids to enhance the solubilities of some gases, with particular emphasis on carbon dioxide.
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