Journal
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume 52, Issue 11, Pages 1643-1647Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023607110010
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Phase transitions and cation mobility in double molybdates K2M2II (MoO4)(3) with M = Mg or Co and the products of their heterovalent doping with scandium(III) and vanadium(V) have been studied. The transition from low to high conductivity in K2MII MoO4)(3) is the result of a two-stage phase transition, whose occurrence is significantly extended in time. Heterovalent substitutions noticeably decrease the heat of the phase transition. The transition to the low-temperature phase is not achieved even after long-term exposure.
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