Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 10, Issue 11, Pages 1311-1314Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2007.07.030
Keywords
cyclic framework; Schiff base complex; [2 x 2] grid; tetracopper(II) complex; distorted coordination center
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A new tetracopper(II) complex [CU4(bsbd)(4)] (bsbd = bis(N-salicylidene)benzene-1,4-diamine) has been prepared and structurally characterized. The complex constructs a [2 x 2] cyclic coordination framework, which inhibits formation of square planar copper(II) centers, and induces distortion to a tetrahedral structure. The effects of the distortions on the absorption spectra are characterized. (c) 2007 Elsevier B.V. All rights reserved.
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